Wilhelm Ostwald(1853 — 1932)

Wilhelm Ostwald

Allemagne, Empire russe

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SciencesScientifique20th CenturyLate 19th and early 20th century, the golden age of physical chemistry and of the professionalization of scientific research in Germany

Wilhelm Ostwald was a Baltic German chemist, one of the founding fathers of physical chemistry. He received the Nobel Prize in Chemistry in 1909 for his work on catalysis, chemical equilibria and reaction rates.

Frequently asked questions

To understand who Wilhelm Ostwald is, you have to picture chemistry at the end of the 19th century, still very empirical. This Baltic German chemist, born in 1853 in Riga, is one of the founding fathers of physical chemistry, a discipline that applies the laws of physics to chemical reactions. What makes him decisive is that he not only defined key concepts such as catalysis (Nobel Prize in 1909), but also gave structure to an entire scientific field with his Textbook of General Chemistry and the journal Zeitschrift für physikalische Chemie. In short, he turned chemistry into an exact, measurable science.

Key Facts

  • Born in 1853 in Riga (then part of the Russian Empire), died in 1932 near Leipzig
  • Co-founder of physical chemistry alongside van 't Hoff and Arrhenius in the 1880s
  • Developed the Ostwald process (1902) for the industrial production of nitric acid from ammonia
  • Received the Nobel Prize in Chemistry in 1909 for his work on catalysis
  • Advocate of “energetics”, a philosophical doctrine that holds energy to be the fundamental reality

Works & Achievements

Lehrbuch der allgemeinen Chemie (Textbook of General Chemistry) (1885-1887)

A foundational treatise that defined and organized physical chemistry as an independent discipline. A major reference for generations of chemists.

Ostwald's Dilution Law (1888)

A mathematical relationship describing the dissociation of weak electrolytes in solution. A cornerstone of the emerging field of electrochemistry.

Theory of Catalysis (1894)

The modern definition of a catalyst as something that speeds up a reaction without being consumed. It earned Ostwald his Nobel Prize.

Ostwald Process (1902)

An industrial method for producing nitric acid by oxidizing ammonia. Still used today to make fertilizers and explosives.

Zeitschrift für physikalische Chemie (co-founded journal) (1887)

The world's first scientific journal dedicated to physical chemistry, co-founded with van 't Hoff. It shaped the community around this new science.

Ostwald Color System (Farbenlehre) (1916-1923)

A rational classification of colors based on measurable principles. It influenced designers and art theorists alike.

Nobel Prize in Chemistry (1909)

An award given for his work on catalysis, chemical equilibria, and reaction rates. The crowning recognition of physical chemistry.

Anecdotes

Ostwald was awarded the Nobel Prize in Chemistry in 1909 for his work on catalysis, but he nearly never became a chemist at all: a passionate painter, he once dreamed of being an artist. Later, he even founded a science of colors and invented a system to classify them, proving he had never truly set down his palette.

The “Ostwald process,” which he developed in 1902, makes it possible to manufacture nitric acid from ammonia. This process, still used today, serves to produce fertilizers that feed a large part of the planet.

Ostwald was for a long time a fierce opponent of the existence of atoms: he believed chemistry could be explained using energy alone, without these tiny invisible particles. He changed his mind around 1909, after Jean Perrin's experiments on Brownian motion proved that atoms really did exist.

Together with his Swedish friend Svante Arrhenius and the Dutchman Jacobus van 't Hoff, Ostwald formed a trio nicknamed the “Ionists” that founded an entirely new discipline: physical chemistry. Together, in 1887, they launched the first scientific journal devoted to the field.

Late in his life, withdrawn to his estate named “Energie” near Leipzig, Ostwald devoted a great deal of energy to promoting an international language (Ido) and to reforming the organization of science. He dreamed of a world where scholars from every country would understand one another instantly.

Primary Sources

Lehrbuch der allgemeinen Chemie (Textbook of General Chemistry) (1885-1887)
Physical chemistry studies the general relationships between the physical properties and the chemical composition of substances.
Nobel Lecture: “Über Katalyse” (On Catalysis) (12 December 1909)
A catalyst is a substance that alters the rate of a chemical reaction without itself appearing in the final products.
Die Mühle des Lebens (The Mill of Life / autobiography Lebenslinien) (1926-1927)
My entire scientific life has been governed by the conviction that energy is the fundamental reality of the world.
Patent for the ammonia oxidation process (1902)
A process for producing nitric acid by the catalytic oxidation of ammonia over a platinum gauze.

Key Places

Riga (Latvia)

Baltic port city where Ostwald was born in 1853 into a Baltic German family. He spent his childhood there and developed his taste for experiments.

University of Dorpat (Tartu, Estonia)

German-speaking university of the Russian Empire where Ostwald studied chemistry and defended his thesis. It was there that he met his first mentors.

University of Leipzig (Germany)

Major German university where Ostwald was professor of physical chemistry from 1887 to 1906. His laboratory attracted students from all over the world.

The “Energie” Estate at Großbothen

Country estate near Leipzig where Ostwald retired after 1906. There he continued his research on colors and died in 1932.

Riga Polytechnic, then Leipzig — Stockholm (Nobel ceremony)

It was in Stockholm that Ostwald received the Nobel Prize in Chemistry in 1909 from the Royal Swedish Academy of Sciences.

See also